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PDF For BLS 1944

BLS® 1944 Hindered Amine Light Stabilizer (HALS)

BLS® 1944 – Hindered Amine Light Stabilizer (HALS)

BLS® 1944 – Introduction: BLS 1944 is a high molecular weight hindered amine light stabilizer. It provides outstanding light stability to many polymers and it also provides long-term stability to polyolefins by a radical trapping mechanism similar to that of hindered phenols. Significant levels of stabilization are achieved at relatively low concentrations. Because of its polymeric structure, BLS® 1944 has a very low volatility (even at high temperatures), low extractability and low migration rate from polymeric substrates. When compounded, BLS® 1944 imparts no negative effects on a substrate’s initial color, its low dust, free-flowing form makes it exceptionally convenient to handle.

Contact Mayzo® at our toll Free number: 1 (800) 449-9068 for more information about our additives for polyolefins.
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Material Description: Hindered Amine Light Stabilizer (HALS)

Chemical Name: Poly[[6-[(1,1,3,3,-tetramethylbutyl)amino]-s-triazine-2,4-diyl][2,2,6,6-tetramethyl -4-piperidyl)imino]]hexamethylylene[(2,2,6,6-tetramethyl-4-piperidyl)imino]]

Empirical Formula: (C35H82N8)x

CAS#: 70624-18-9

Chemical Structure:

Physical Properties:

Appearance: White to yellow granular powder
Molecular Weight: Mn> 2500
Melting Range: 100 – 135°C

Solubility at 20°C (g/100ml solvent):

Solvent

Solubility

Acetone > 50%
Benzene > 50%
Chloroform > 50%
Ethanol < 0.1%
Ethyl Acetate > 50%
Hexane 41%
Methanol 3%
Methylene Chloride > 50%
Toluene > 50%
Water < 0.01%

Applications: BLS® 1944 is a polymeric hindered amine light stabilizer offering excellent protection against ultraviolet degradation. BLS® 1944 areas of application include polyolefins (polypropylene, polyethylene), olefin copolymers such as EVA as well as blends of polypropylene with elastomers. In addition, BLS® 1944 can be highly effective in polyacetals polyamides, polyurethanes, flexible and rigid PVC, as well as PVC blends and in some styrenic elastomer and adhesive specialty applications.

Advantages

  • Free-flowing, low dust
  • Excellent resistance to extraction
  • Excellent long-term light stability in thick cross sections specifically polyethylene applications
  • Excellent long-term light stability, particularly in thin articles like fibers and films
  • Low volatility
  • FDA clearances
  • Ease of compatibility with other stabilizers

Loading Instructions: TThe loading data and results are based on laboratory work (and field testing) under controlled conditions and do not necessarily indicate the result that the buyer or user will attain. For this reason we strongly recommend testing of your own system under the actual conditions of processing and end-use prior to full scale testing. The recommended loading concentrations in thick sections of HDPE, LLDPE, LDPE and PP range between 0.05% and 0.6% depending on substrate, processing conditions, and long-term stability requirements. Concentration levels of BLS® 1944 in films like LLDPE and LDPE range from 0.1% to 1%, and in tapes like PP and HDPE, BLS® 1944 concentrations range between 0.2% and 0.8%. Concentrations levels of BLS® 1944 in fibers of PP range between 0.1% to 1.0%. Exact loading must be determined by compositions of the specific polymer system. The presence of a UV absorber like BLS® 1328 is recommended in unpigmented articles or slightly pigmented articles or to improve light fastness of certain organic pigments.

Packaging: BLS® 1944 is available in granular form in a 40 kg (88.16 pound) fiber drum, net weight, with an inner PE liner.

Storage: This product may be stored up to two years in a sealed container. Containers should be stored in a cool, dry area. Extended storage at elevated temperatures or exposure to direct heat or sunlight could reduce product life. Keep containers sealed when not in use.

Toxicity & Safety: This material is not intended for use in products for which prolonged contact with mucous membranes or abraded skin, or implantation within the human body is specially intended, unless the finished product has been tested in accordance with the Food and Drug Administration and/or other applicable safety testing requirements. Because of wide range of such potential uses, Mayzo, Inc. is not able to recommend this material as safe and effective for such uses and assumes no liability for any such uses. Read and understand the Material Safety Data Sheet before using or handling this product.

FDA Regulations: Supplement

Existing Regulations

Maximum Concentration

Thickness

Food Allowed

Temperatures Allowed

Stabilizer for polymers, 178.2010 Poly[[6-[(1,1,3,3,-tetramethylbutyl)amino]-s-triazine-2,4-diyl][2,2,6,6-tetramethyl piperidyl)imino]]hexamethylylene[(2,2,6,6-tetramethyl-4-piperidyl)imino]]
Polypropylene complying with 177.1520 0.3% no restrictions no restrictions no restrictions
Polyethylene complying with 177.1520 that has a density of >0.94 g/cc 0.2% no restrictions no restrictions no restrictions
Polyethylene complying with 177.1520 that has a density of >0.94 g/cc 0.3% no restrictions no restrictions, but with fatty foods the finished article must have a thickness of at least 18.9 liters 212°F
Olefin polymers and copolymers complying with 177.1520, items 3.1, 3.2, 3.3, 3.4, 3.5, 3.6, and 4 0.3% no restrictions no restrictions, but with fatty foods the finished article must have a thickness of at least 18.9 liters 212°F

BLS® 1944 Hindered Amine Light Stabilizer (HALS)



The information contained herein is believed to be reliable. However, Mayzo, Inc. makes no warranty, whether expressed or implied, including warranties of merchantability or of fitness for a particular purpose, for the product or products referred to herein. No statements or recommendations contained herein are to be constructed as inducements to infringe any relevant patent, now or hereafter existence. Under no circumstances shall Mayzo, Inc. be liable for incidental, consequential, or other damages from alleged negligence, breach of warranty, strict liability, or any other legal theory, arising out of the use of handling of the product or products referred to herein. The sole remedy of the buyer and sole liability of Mayzo, Inc. for any claims shall be limited to the buyers purchase price of the product which is subject of the claim or the amount actually paid for each product, whichever is less. Technical advice furnished by seller shall not constitute a warranty, which is expressly disclaimed, all such advice being given and accepted at the buyers risk.